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Download scientific diagram | Schematic illustration of microstructures and Gibbs free energy curves. (a) Starting from pure metals, the atoms can form SS, IM or SS + IM microstructure. IMs are marked in red boxes. (b) Gibbs free energy of HEA with the composition x 0 corresponding to different microstructures. Gibbs free energy of IMs are fixed points at the corresponding stoichiometries. The SS + IM(B) multiphase microstructure has the lowest Gibbs free energy. The changes in Gibbs free energy by perturbation is illustrated. (c) Gibbs free energy curves of HEA with more IMs. As the number of elements increases, the number of possible IMs increases and the HEA tends to have multiphase microstructure. (d) Gibbs free energy curves of HEA at different tem perature. The SS has lower Gibbs free energy at higher temperature (High Temp. curve in red) than at lower temperature (Low Temp. in light red). (For interpretation of the references to color in this figure legend, the reader is referred to the web version of this article.) from publication: Phase stabilities of high entropy alloys | A perturbation model is used to evaluate the phase stabilities of high entropy alloys. The calculation results can successfully predict the phase stabilities of many high entropy alloys and shows that stable single phase high entropy alloys are rare. The effect of increased… | Entropy, Alloys and Intermetallics | ResearchGate, the professional network for scientists.

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